"A 2020 heat wave unleashed methane emissions from prehistoric limestone in two regions stretching 375 miles, study says
"The difference is that thawing wetlands releases “microbial” methane from the decay of soil and organic matter, while thawing limestone — or carbonate rock — releases hydrocarbons and gas hydrates from reservoirs both below and within the permafrost, making it “much more dangerous” than past studies have suggested.
Nikolaus Froitzheim, who teaches at the Institute of Geosciences at the University of Bonn, said that he and two colleagues used satellite maps that measured intense methane concentrations over two “conspicuous elongated areas” of limestone — stripes that were several miles wide and up to 375 miles long — in the Taymyr Peninsula and the area around northern Siberia.
The study was published by the Proceedings of the National Academy of Sciences.
Surface temperatures during the heat wave in 2020 soared to 10.8 degrees Fahrenheit above the 1979-2000 norms. In the long stripes, there is hardly any soil, and vegetation is scarce, the study says. So the limestone crops out of the surface. As the rock formations warm up, cracks and pockets opened up, releasing methane that had been trapped inside.
The concentrations of methane were elevated by about 5 percent, Froitzheim said. Further tests showed the continued concentration of methane through the spring of 2021 despite the return of low temperatures and snow in the region.
“We would have expected elevated methane in areas with wetlands,” Froitzheim said. “But these were not over wetlands but on limestone outcrops. There is very little soil in these. It was really a surprising signal from hard rock, not wetlands.”
The carbonates in the outcroppings date back 541 million years to the Paleozoic era, according to the U.S. Geological Survey.
“It’s intriguing. It’s not good news if it’s right,” said Robert Max Holmes, a senior scientist at the Woods Hole Research Center. “Nobody wants to see more potentially nasty feedbacks and this is potentially one.”
“What we do know with quite a lot of confidence is how much carbon is locked up in the permafrost. It’s a big number and as the Earth warms and permafrost thaws, that ancient organic matter is available to microbes for microbial processes and that releases CO2 and methane,” Holmes said. “If something in the Arctic is going to keep me up at night that’s still what it is.” But he said the paper warranted further study.
The geologists who wrote the report usually study things such as tectonic plate boundaries and the way those geologic plates fold over one another. But they have worked in the Arctic and that has piqued their interest.
The biggest sources of methane in the world are agricultural, such as rice growing, and leaks from hydraulic fracturing in the U.S. Permian Basin in Texas and New Mexico. But Froitzheim said that in the permafrost “the question is: how much will come, and we don’t really know.”
Normally the frozen permafrost acts as a cap, sealing methane below. It also can lock up gas hydrates, which are crystalline solids of frozen water that contain huge amounts of methane. Unstable at normal sea-level pressure and temperatures, gas hydrates can be dangerously explosive as temperatures rise.
The study said that gas hydrates in the Earth’s permafrost are estimated to contain 20 gigatons of carbon. That’s a small percentage of all carbon trapped in the permafrost, but the continued warming of gas hydrates could cause disruptive and rapid releases of methane from rock outcrops.
“It will be important to continue to compare methane in future years to really pinpoint how much additional geologic methane is being emitted to the atmosphere as the permafrost thaws," said Ted Schuur, professor of ecosystem ecology at Northern Arizona University. “We know the heat wave was real, but whether it triggered the methane release cannot be determined without additional years of methane data."
The Arctic has also delivered other sobering news. Polar Portal, a website where Danish Arctic research institutions present updated information about ice, said last week that a “massive melting event” had been big enough to cover Florida with two inches of water."
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